40% of the Monk's single elemental resistances from items is converted to resistance to all elements.
Harmony is a Monk passive skill, unlocked at level 45. In patch 2.1, it replaced One with Everything (see below).
The 40% conversion means that an item that has +160 Fire resistance will instead grant 64 all resistances and additional 96 Fire resistance, to a total of 160 Fire resistance and 64 to all other elements (including Physical).
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This article contains information that is no longer relevant to gameplay, but is kept here for informational purposes.
Prior to patch 2.1, this skill was named One with Everything: it was making the resistances to all seven elements always equal to the highest resistance the Monk had (i.e. if the highest resistance was Fire with 2100, all other resistances would be escalated to 2100). It was the most used of the Monk's skills: with properly assembled gear (all resistances + same element resistance on each piece) it effectively increased all resistances by +160%. However, developers felt that this was making the skill look mandatory and undermined the build diversity, eventually replacing OwE with Harmony.